Glass is one of the most versatile materials
used not just in many industries but also in daily life. Glass has many uses because of its
transparency, high resistance to chemical attack, effectiveness as insulator, ability
to contain a vacuum and many other properties. Glass is also one of the oldest
materials in the world. Archaeologists have found evidence of man-made glass in
Egypt which dates back to 6000BC. On the other hand, flat glass was mentioned
as early as 290 A.D. (Shreve & Brink Jr., 1977)
Glassworks in the United States were founded
in 1608. The first glass rolling process dates back to 1688 in France. Joseph Paxton's Crystal Palace at the Great Exhibition
of 1851 marked the beginning of the discovery of glass as a building material.
The revolutionary new building encouraged the use of glass in public, domestic
and horticultural architecture. However, glass back then was very
expensive because it was considered an art with closely guarded secret formulas
and empirical processes of manufacturer based from rule of thumb and
experience. It was not until the
beginning of the 19th century that glass has become relatively
cheaper made possible by the invention of machine process that can mass produce
glass. The invention of the first bottle machine in 1904 by Owens also marked
the rapid developments of machine processes for glass production. In 1952, Sir
Alastair Pilkington invented the float process that greatly reduced the
laborious work of flat glass production. Before
the development of float process, larger sheets of plate glass were made by casting a large puddle of
glass on an iron surface, and then grinding and polishing both sides for
smoothness and clarity - a very expensive process.
From 19th century onwards,
scientists and engineers enter the field with increasing numbers and new
products appear as a result of intensive research. Today, glass making is a modern, hi-tech
industry operating in a fiercely competitive global market employing all the
tools of modern science and engineering in the production, control and
development of its many products.
Nowadays, in general, commercial
glass products fall into numerous classes according to composition:
1. Fused
Silica or vitreous silica. This class of glass is made from high-temperature
pyrolysis of silicon tetrachloride. It has high chemical and thermal resistance
because of its low expansion and a high softening point. This kind of glass is
also extraordinary transparent to ultraviolet radiation.
2. Alkali
Silicates. They are the only two-component glasses of commercial importance.
These are soluble glasses used in solutions. This glass type is widely used as
an adhesive for paper in the manufacture of corrugated-paper boxes.
3. Soda-lime
glass. The soda-lime-silica represents by far the largest percentage of glass
made today. It is used for windows, transparent fixtures, and containers of all
kinds.
4. Lead
Glass. Commonly known as lead crystal, lead
glass is used to make a wide variety of decorative glass object. It is made by
using lead oxide instead of calcium oxide, and potassium oxide instead of all
or most of the sodium oxide. It has also great importance in optical
work because of its high index of refraction and high dispersion.
5. Borosilicate
Glass. It
is made mainly of silica and boric
oxide with smaller amounts of the alkalis (sodium and potassium oxides) and
aluminum oxide. This type of glass has relatively low alkali content and
consequently has excellent chemical durability and thermal shock resistance. As
a result, it has many diversified applications.
6. Special
glasses. Other types of glasses not mentioned above fall under special glasses.
It includes
glass fibers used for reinforcement, optical glass used in scientific
instruments, sealing glass used to protect metals, technical glass used in
electronics and many more types used in emerging industries.
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